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Small Surface Water Systems Use Membrane Filters
To Remove Disinfection By-Product Precursors

    

By David Pearson, General Manager, PCI Membrane Systems, Inc.

Providing safe drinking water in small communities is made more difficult when the only water source available is surface water laden with organic matter, and when skilled labor required to run what amounts to a miniature chemical plant is neither readily available nor affordable.

Traditional methods of removing humic color from raw water - including flocculation, clarification and other chemical-based approaches - can require high staffing levels. The plant size required is generally large and cumbersome, and the transporting of equipment and chemicals to remote sites can sometimes be impossible.

Fortunately, a new nanofiltration membrane filtration process, now available in North America from PCI Membrane Systems, Inc., Milford, OH, promises effective water treatment without high capital costs or heavy labor requirements. The Fyne Process, as it is called, was first used in Scotland and has become the water treatment technology of choice for rural communities with organic-laden surface water from lakes or rivers as the water source. Today, there are over 30 PCI installations running or on order with the three Scottish Water Authorities. Systems as small as 1.8 gal/min (10 m3/day) and as large as 260 gal/min (1420 m3/day) are currently operating. More recently, the first few North American installations have been very successful.

SITUATION ANALYSIS

All along the rocky Canadian Shield, in Alaska, and in the northeast U.S., it is difficult to drill wells for drinking water, so smaller communities often rely on surface water that tends to be heavy with dissolved organic materials. Heavy chlorination is required and that can lead to high TTHM (trihalomethane) and HAA(5) (haloacetic acid) concentrations in the treated water.

Studies have shown that TTHMs and HAA(5)s may be carcinogenic and their presence also has been linked to miscarriages, so Canadian and US regulations limit the presence of some or all of these byproducts in municipal water systems. Until recently, many small communities that rely on surface water for drinking have been exempt from these limits. However, new, more stringent drinking water rules in North America - including Stage 1 of the Disinfection By-Products rule in the U.S., and new regulations in the Canadian province of Ontario - are forcing small, rural communities to seek solutions that effectively remove organic matter prior to chlorination.

HOW THE PROCESS WORKS

The Fyne Process is based on a particular membrane filtration process known as nanofiltration. This type of filtration allows inorganic ions to pass through the membrane with the filtrate. Organic compounds (such as humic and fulvic acids), which cause the high color content and disinfection by-products, are held back, along with oocysts, bacteria viruses, and many undesirable metals, including manganese and iron.

There are two membrane configurations (tubular or spiral) that may be specified, depending on plant capacity, raw water quality and recovery required.

Spiral nanofiltration membranes are usually required in large volume systems, but tubular membranes are preferred whenever possible. That’s because spiral systems require feed-water pre-filtration and frequent chemical cleaning. Tubular membranes, which can be kept clean by periodically passing a foam ball down the length of the tube, need chemical cleaning only 3 to 4 times per year.

In a tubular system, the filtration process starts with raw water, which is drawn into the system through a coarse screen and pumped through modules consisting of proprietary half-inch tubular membranes to remove the undesirable dissolved organic materials. A portion of the input water (the filtrate) crosses the membrane and then is ready for chlorination and delivery to consumers. The concentrate or retentate continues to flow through the membrane tube, carrying much of the retained organic matter with it. Because no chemicals are used in the process (in contrast to chemical flocculation and clarification systems), the discharge water is merely a more concentrated form of raw water, which can be returned to the source. Thus, a tubular membrane system achieves between 70% and 90% recovery, with none of the expense associated with coagulant treatment or the high maintenance costs associated with spiral membranes.

Operation is simple and automated, so the plant can run unattended, with intervention on no more than a weekly basis for routine maintenance. Pressure and flow data are logged continuously and the system can even be monitored remotely when an outside telephone line is available.

EPA VERIFICATION

A study published as part of the EPA’s Environmental Technology Verification (ETV) Program® has verified the performance of a Fyne Process membrane filtration plant tested in Barrow, AK. The study confirmed that the plant could produce water that easily met the Disinfection By-Product standards set by the EPA’s stringent Stage 1 D/DBP Rule.

Barrow’s untreated water had an average total organic carbon (TOC) level of 15mg/l and with moderate turbidity. Over the 57-day test period, the average TTHM concentration was reduced from 535 µg/L in chlorinated raw water to just 31 µg/L in water chlorinated after nanofiltration in the Fyne Process test plant. Average HAA(5) concentrations were reduced from 398.4 µg/L to just 6.2 µg/L. The membrane system also reduced UV254 absorbance, total organic carbon, and turbidity - measures of water color and clarity - by 97.5%, 95.4%, and 98.3%, respectively.

The ETV program was implemented to assist in the development of innovative, cost-effective environmental technologies, including packaged drinking water treatment systems like the Fyne Process. The testing was performed by the University of Alaska, in cooperation with the University of New Hampshire, which is a qualified Field Testing Organization under this ETV program.

OTHER NORTH AMERICAN RESULTS

Two Canadian installations also are demonstrating the effectiveness of the Fyne Process.

The first system was installed in Nova Scotia in February 2000, and has been running full-time ever since. A second, smaller system began operating in June 2000 at The Tl'azt'en Nation community of Middle River in British Columbia.

Chapel Island is a small First Nation Community located east of Halifax, Nova Scotia. The plant was installed with a rated capacity 26.2 gal/min (143 m3/day), with a 20-year projected demand of 56 gpm (305m3/day). The new installation replaced a small packaged water treatment plant using coagulation and filtration technology that required expansion and significant refurbishment.

Raw water is taken from a shallow lake with typical TOC levels of 8 mg/l and color normally in the 40–100 TCU range. The intake is taken through a 3-mm screen and piped to a sump under the water treatment plant room. There is no additional filtration or treatment prior to the membrane filter.

Reject water, which as noted is merely a more concentrated form of raw water with no chemicals added to it whatsoever, is fed back to the lake. When a chemical clean is necessary, these chemicals are sent by separate drain to a wastewater treatment lagoon where sludge from the conventional flocculation and clarification package plant (now removed) had previously been sent.

The system was competitively bid, and although initial capital costs were higher, the Fyne process was chosen from a variety of different treatment methods because of its lower overall life cycle cost. Running cost saving are realized as the Fyne process uses no chemicals in the production of the water and requires significantly less attention, allowing hard-pressed community maintenance staff to attend to other demands. The system also is designed to allow simple plant expansion. Additional capacity can be added easily as and when required to meet changing needs.

The plant has been run above its design capacity since installation, producing on average 155 m3/day, operating each day for 21.4 hrs on process. It was cleaned only twice in the first 12 months after start up and was to have been cleaned for the third time around its first anniversary. The plant did experience a significant increase in pressure over a short period, when cleaning of the inlet works created an influx of sediment into the raw water sump. Although the sediment remained in the inlet line for a number of days, the membrane plant continued to produce its rated volume of water - albeit at a higher operating pressure - until its second partial clean a month after the incident. This experience only served to prove the resilience of the Fyne Process to upsets in raw water quality, for whatever reason.

MIDDLE RIVER PERFORMANCE

The Tl'azt'en Nation community of Middle River is a small village located on a river northwest of Prince George, British Columbia. An isolated community two hours from the nearest town, the site is a prime candidate for the benefits of the Fyne process. The plant operated initially as a 6-month pilot to test its suitability for operation in a remote community. An engineering firm, CH2M Canada, monitors performance of the system for the Department of Indian and Northern Affairs Canada. At the end of the pilot period it was decided to purchase the unit.

The Fyne plant, which has a design capacity of 5.8 gal/min (22 l/min), operates with 6 PCI C10 filtration modules. Raw water is drawn from the nearby river. Lift pumps provide water to the plant with a 2.5-mm screen at the intake.

The Fyne plant was delivered in and continues to operate in a heated and ventilated 40-ft container, complete with membrane wash tank, chlorine dosing and contact tanks, and 1100-gal storage. Reject from the plant is sent to a sump tank overflowing back to the river. To protect the environment, a separate tank is used to contain washing chemicals that can then be taken away by tanker truck.

Since installation, performance of the system has been very similar to the one at Chapel Island. Corrected pressure rose at a constant rate until the first membrane clean, which was scheduled for four months after first operation of the plant. This clean was not entirely effective and a second clean was performed shortly after to establish if any significant irreversible fouling was occurring. Cleaning concentrations and duration were increased and the plant returned to within 96% of its early normalized flux.

Regular analysis of feed water and filtrate is also made. TOC reductions improved from 30% to 70% over the first 200 hours of operation and have remained consistently low. Iron and manganese were also significantly reduced. While data on TTHM concentrations are limited, formation-potential tests indicate levels well within current Canadian guidelines.

As evidenced in these North American installations, the Fyne Process offers distinct advantages:

  • Cost-effective for small and medium-sized systems requiring removal of disinfection by-products precursors; yields chlorinated water below the limits of the EPA D/DPD Rule Stage 1 for TTHM and HAA(5).
        
  • Low staffing requirement; the Fyne Process can be fully automatic, including the cleaning cycle. The plant can operate effectively unsupervised.
        
  • Tolerant to wide variations in raw water quality; does not need adjustment when the feed water quality changes.
       
  • High recovery rate minimizes waste of feed water.
       
  • No chemical sludges generated. Mechanical cleaning means cleaning chemical usage is minimized.
       
  • Compact design. Fyne plants are mounted on a steel frame or skid, and units as large as 100 m3/d /(18 gpm) can be fitted into a standard 20ft or 40ft. container. Transportation to remote areas is possible by truck, or even by helicopter.
       
  • Single-phase supply. Optional single-phase electrical supply for smaller plants to suit the remotest of sites.
       
  • Built and tested off-site. On-site work is kept to the minimum of introducing a power supply and connecting the unit.
      
  • Performance guaranteed for capacity and water quality, from a company with extensive colored water operational experience and 25 years in other industrial applications.

PCI expects that the Fyne Process, with its particular advantages for remote, small communities, will be accepted across North America as the process system of choice, just as it has been in Scotland.
 

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